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Sodium Nitrate Manufacturers, SDS MSDS Sheet

Specifications of Sodium Nitrite and Sodiium Nitrate from Manufacturers
Sodium Nitrite BP USP IP ACS Analytical Reagent FCC Grade Manufacturers

Sodium Nitrate SDS MSDS Sheet, Material Safety Data Sheet

1. Product Identification

Synonyms: Sodium Nitrate; Chile saltpeter; soda niter; Sodium saltpeter; Nitric acid sodium salt; Nitratine.
CAS No.
: 7631-99-4
EINECS: EC Number: 231-554-3
Molecular Weight: 84.99
Chemical Formula: NaNO3

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008:

Oxidizing solids Category 3
Acute Toxicity Oral Category 4
Skin irritation Category 2
Eye irritation Category 2A
Specific target organ toxicity - single exposure Category 3, Respiratory system

Labeling according to GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Oxidizer
Oxidizing Solid

GHS Label Elements
Irritant
Irritant

Signal Word: Warning

Hazard Statements:
H272: May intensify fire; oxidizer.
H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.

Precautionary Statements
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P220: Keep/Store away from clothing/…/combustible materials.
P221: Take any precaution to avoid mixing with combustibles.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264 Wash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P302+P352: IF ON SKIN: Wash with soap and water.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
P370+P378: In case of fire: Use … for extinction.
P362: Take off contaminated clothing and wash before reuse.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
O = Oxidizing
Xi = Irritant
R 8 = Contact with combustible material may cause fire.
R36 = Irritating to eyes.

3. Composition/Information on Ingredients

Ingredient: Sodium Nitrate
CAS No.: 7631-99-4
EINECS: EC Number: 231-554-3
Percent: 97 - 100%

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

5. Fire Fighting Measures

Flammability of the Product: The product is not flammable but it is an oxidizer.
Products of Combustion: It emits toxic oxides of carbon and oxides of nitrogen when heated to decomposition.
Fire: Sodium nitrate is an oxidizer.
Explosion: Slightly explosive in presence of heat.
Fire Extinguishing Media
: Water spray. Use means suitable for extinguishing surrounding fire. Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information
 In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes.
It may accelerate burning when involved in a fire. Increases the flammability of any combustible material. May ignite Combustibles (wood, paper, clothing, etc.). Flames up when heated to 540 deg. C. Mixture with charcoal ignites on heating. Contact with combustible or organic materials may cause fire.
It will react explosively with hydrocarbons. Interaction of nitrates when heated with amidosulfates (sulfamates) may become explosively violent owing to liberation of dinitrogen oxide and steam. Mixtures of sodium nitrate with powdered aluminum or its oxide were reported to be explosive. Mixtures of sodium nitrate and barium thiocyanate may explode. Mixture with sodium nitrate and powdered antimony explode. Mixture of sodium nitrate and sodium thiosulfate or sodium phosphinate explode.

6. Accidental Release Measures

Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow evacuating through the sanitary system.

7. Handling and Storage

Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage or contact with oxidizing material and combustible substances.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Sodium nitrate is white crystals or powder or granules.
Odor: None
Solubility: Readily soluble in water
pH: 6-9 at 1% solution at 25 C (77F)
Density: 2.26 gm/cc
Molecular Weight: 84.99
Molecular Formula: NaNO3
% Volatiles by volume @ 21C (70F): 0
Boiling Point: Decomposes at 380C
Melting Point: 307C

10. Stability and Reactivity

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits toxic oxides of nitrogen along with sodium oxide when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong acids, Strong reducing agents, powdered metals, Organic materials. Avoid all combustible materials and metals. Contact with barium rhodanide, boron phosphide, cyanides, sodium thiosulfate, sodium hypophosphite, sulfur plus charcoal, powdered aluminum and aluminum oxide may cause an explosion.
Conditions to Avoid
: Moisture, Heat, Incompatibles.

11. Toxicological Information

Toxicity to Animals:
LD50 Oral - Rat - 3.430 mg/kg
LD50 Dermal - Rat - > 5.000 mg/kg
LD50 Intravenous - Mouse - 175 mg/kg
Special Remarks on Toxicity to Animals: Not available.
Carcinogenic Effects: Not a reported carcinogen.
Mutagenic Effects: Mutagenic for bacteria and/or yeast. May cause damage to blood.
Teratogenic Effects: Not available.

12. Ecological Information

Toxicity to fish static test LC50 - Gambeson affinis (Mosquito fish) - 6,650 mg/l - 96 h
Fathead minnow: GT 1000 mg/L 96-h LC50; Water flea: GT 1000 mg/L LC50
Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - 6,000 mg/l - 24 h
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. Small amounts of this material may be suitable for sanitary sewer or trash disposal.

14. Transport Information

DOT (USA) & ADR/RID
UN-Number: 1498 Class: 5.1 Packing group: III
Proper shipping name: Sodium nitrate
Marine pollutant: No
Poison Inhalation Hazard: No
IMDG
UN-Number: 1498 Class: 5.1 Packing group: III EMS-No: F-A, S-Q
Proper shipping name: Sodium nitrate
Marine pollutant: No
IATA
UN-Number: 1498 Class: 5.1 Packing group: III
Proper shipping name: Sodium nitrate

15. Regulatory Information

USA:
SARA Codes: CAS # 7631-99-4: flammable.
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
Section 313: Sodium nitrate CAS-No.: 7631-99-4
SARA 311/312 Hazards: Reactivity Hazard, Acute Health Hazard.
TSCA: CAS# 7631-99-4 is on the TSCA Inventory.
Health & Safety Reporting List: None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules: None of the chemicals in this product are under a Chemical Test Rule.
Section 12b: None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule: None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs: None of the chemicals in this material have an RQ.
California Prop 65: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

Canada - DSL/NDSL
Canadian WHMIS Classifications: C, D2B
CAS# 7631-99-4 is listed on Canada's DSL List.
This product has a WHMIS classification of C, D2B.
CAS# 7631-99-4 is listed on Canada's Ingredient Disclosure List.

Section 16 - Additional Information

Disclaimer:
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Our company provides this Sodium nitrate SDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This Sodium nitrate MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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Sodium Nitrate Manufacturers:

MUBY CHEMICALS GROUP
DONGRI-CHINCHBUNDER, MUMBAI 400009, INDIA
TEL: (OFFICE) 91-22-23770100, 91-22-23726950, 91-22-23774610, 23723564.

e-mail: info@mubychem.com

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